- Get picture from camera when motion detect.
- Send this pic to Cloud Face to processing ““Who is this?””
- Cloud Face return value to SmartThings (control device by SmartApp)
You can see this Cloud API https://www.kairos.com/features
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It would be a fun project (and I know of various proofs-of-concepts that have been done, though not specifically integrated).
I doubt the effort is worthwhile though.
- This type of face recognition is easily fooled by a two-dimension photograph.
- The delay (and false negatives due to lighting or whatever) is much less convenient than using identification based on a presence sensor, phone, and/or PIN entry
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-Security is a difficult problem.
-However, identifying to control your favorite TV channel or room temperature is possible.
-Level: Home Automation->Smart Home -> Intelligent Home (AI Home) [House in the future] 
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