Samsung itself no longer makes SmartThings branded sensors. It is a platform that works with sensors from many different companies. For customers in many different countries. So there’s just no one answer to your question: different things will work for different people. 
Some people have almost all Zwave devices.
Some people have only Zigbee devices.
Many people have a mix.
Wi-Fi typically is not used for battery powered sensors because it requires much more battery power than an identical sensor that utilizes a Zigbee or thread or even Z wave radio.
A sensor using one of those first three protocols will have a battery life typically of one and a half to two years, regardless of the platform it’s being used with and regardless of the company that manufactured it.
A Wi-Fi sensor with identical features will probably have a battery life of about three months. So they just aren’t very popular because people don’t want to change batteries that often.
BUT SOME PEOPLE DO USE WIFI BATTERY POWERED SENSORS
There is one company, Shelly, which has been working with the Wi-Fi standards group to try to improve battery life for its battery powered Wi-Fi sensors, but even those typically get about eight months. Really good for Wi-Fi, but not really good for this device class.
Still, people who don’t want to get a hub might use Shelly Wi-Fi sensors because those are the ones that will work without a hub.
AND MATTER ADDS EVEN MORE POSSIBLE FREQUENCIES AND PROTOCOLS
Yet another option is to use sensors That work with their own company’s “matter bridge”. In that case, the connection to SmartThings will probably be via Wi-Fi, but the individual sensors might use Bluetooth, Zigbee, or a proprietary frequency, or a proprietary protocol via 433 MHz. Or really anything else. SmartThings will talk to the bridge and the bridge will talk to the individual sensors, so SmartThings doesn’t care what protocol those use. That option is becoming much more popular.
SUMMARY: DIFFERENT PEOPLE USE DIFFERENT PROTOCOLS
So there just isn’t any “mainly” about it. One of the reasons that SmartThings became as popular as it did is because it worked with so many different third-party products and people could choose the ones that worked best for them.