A Sylvania smart light of any model can only belong to one coordinator. So either the Sylvania gateway or the SmartThings hub, but not both for any one light. The Sylvania gateway does not talk to the SmartThings hub. So if you use the gateway that just becomes a completely separate system from anything you have on SmartThings.
As far as the Sylvania switches or any of the other battery powered switches, you can put them anywhere in each one can control lights. So you can certainly create a virtual three-way that way.
You probably already read this, but hereās the FAQ on switches and smart bulbs:
I donāt know the specific limitations if you are using just the Sylvania gateways, but hopefully someone will chime in who does.
As far as color controls, there are options to do the color changes from SmartThings. Again, if you are using the lights with SmartThings you wonāt be able to use the Sylvania app with them at all. But when you are using them with SmartThings, the official features donāt really handle groups very well. So you will need to use custom code, either one of the custom lighting smartapps or Core. But you should be able to do it.