Legrand radiant vs. Lutron Caseta

Both are good systems, but the LeGrand radiant line is intended to work with their own Intuity home automation platform and there is no integration with SmartThings at all.

Lutron offers the SmartBridge ( note: for technical reasons, this is a bridge, not a hub, just like the Philips Hue Bridge). With the SmartBridge, you can have an official Lutron Caseta integration with SmartThings, as well as with IFTTT, Amazon Alexa, Google Home, and a number of other partners.

Again, they are both good systems, but if you get radiant then you will be using their Intuity platform. Not SmartThings. Legrand Intuity uses a manufacturer proprietary profile which is not compatible with anything else.

Lutron also uses a proprietary protocol, but they offer their SmartBridge product to allow integration with many other systems.