Home Automation "Modes"

Yep.

At the time of this posting, Alexa Routines cannot be triggered from most Switches, and that includes the ones connected to smartthings.

It can be triggered from a Contact Sensor, a motion sensor, or a lock. Physical or virtual.

So the trick is to have a virtual device of a kind that Alexa will use to trigger a routine and then have your virtual switch change the state of the virtual sensor/lock.

Your options will be somewhat different, depending on whether you have a Smartthings/Aeotec hub, but the basic idea is the same.

See the community FAQ:

FAQ: Can I trigger an Echo Action without Speaking to It?

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