On/Off is backward when I use Leviton VRPD3-1LW with SmartThings v2

That is a very old device, and does not appear to have any configurable parameters. Check with Leviton support to be sure.

https://www.cd-jackson.com/index.php/zwave/zwave-device-database/zwave-device-list/devicesummary/199

If it does have configurable parameters, you can use the Z wave tweaker to set them:

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