Have one light switch trigger another light?

Unfortunately, the SmartThings hub doesn’t support setting direct associations yet, so you’ll have to use a third-party device to setup the direct associations (eg. switch on wall triggers different device).

Alternatively, you can use a SmartApp like The Big Switch which can introduce a considerable delay and requires the SmartThings hub to be available (eg. it doesn’t work if the Internet connection gets lost).

You can pick up the Aeon Labs Minimote for ~$45 and follow the steps in the post linked below to setup direct associations:

Coming from the Vera line of products, direct association is one of the many things I miss in the ST Hub.