Executing Scene on multiple locations

Repeaters are repeaters, and only for the one network they are on. It doesn’t change the total number of hops available. (4 for zwave, 15 into the hub for the zigbee protocol that SmartThings uses and 15 out again.)

It’s not uncommon with certain types of construction, particularly cement or adobe, that you may require one hub per floor.

So at that point you are in A similar situation to automating an outbuilding.

http://thingsthataresmart.wiki/index.php?title=How_to_Automate_an_Outbuilding

As discussed in that article, You can use IFTTT, WebCore, or a LAN connected device recognized by both hubs like a Philips Hue bridge to cause events on one hub to trigger events on another. But there may be some lag and setup takes some thinking through. For a good night use case that may be acceptable. Have a virtual “good night” switch on one hub trigger a virtual “good night” switch on the other, and then trigger all the good night events off of those.