Does Hue smart plug work as Zigbee repeater?

They do work as Zigbee repeaters.

At present there is no way to see the Zigbee routes for a smartthings account except by adding a third party mapping utility, and that’s a fairly complex technical task. :disappointed_relieved:

The following FAQ is almost 10 years old so some of the details may be different, but the basic approach would be the same.

FAQ: Mapping your ZigBee network with Digi's XCTU

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